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Synthesis, crystal structure and photoluminescence of [Rh(III)(phpy)₂(dithiooxamide)]Cl (phpy = 2-(2-pyridyl)phenyl)

Author:
Vogler, Arnd, Bodensteiner, Michael
Source:
Zeitschrift für Naturforschung 2019 v.74 no.5 pp. 405-408
ISSN:
1865-7117
Subject:
cations, crystal structure, methylene chloride, phosphorescence, photoluminescence, rhodium
Abstract:
The salt [Rh(III)(phpy)₂(dtoxa)]Cl with phpy = 2-(2-pyridyl)phenyl anion and dtoxa = dithiooxamide has been characterized by its crystal structure and its electronic spectra. Since Rh(III) is rather redox-inert, the lowest-energy excited state of the complex cation is of the IL (dtoxa) type. In the solid state as well as in solution the complex is luminescent and displays a dtoxa IL phosphorescence at λₘₐₓ = 607 nm with φϕ = 10⁻³ and τ = 3.7 ns in CH₂Cl₂.
Agid:
6400303