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Binuclear nickel carbonyls with the small bite chelating diphosphine ligands methylaminobis(difluorophosphine) and methylenebis(dimethylphosphine): formation of NiNi double bonds in preference to ligand cleavage

Author:
Liu, Ling, Zhang, Xiuhui, Li, Zesheng, Li, Qianshu, King, R. Bruce
Source:
RSC advances 2016 v.6 no.20 pp. 16131-16140
ISSN:
2046-2069
Subject:
chemical bonding, density functional theory, energy, iron, isomers, ligands, nickel
Abstract:
The structures and thermochemistry of the triads of binuclear nickel carbonyl complexes (bid)Ni₂(CO)ₙ (n = 6, 5, 4) and (bid)₂Ni(CO)ₙ (n = 4, 3, 2) of the small-bite bidentate chelating diphosphines CH₃N(PF₂)₂ and (Me₂P)₂CH₂ have been investigated using density functional theory. The lowest-energy structures of the carbonyl-richest (bid)Ni₂(CO)₆ and (bid)₂Ni₂(CO)₄ structures have long Ni⋯Ni distances indicating the lack of direct nickel bonds. Similarly, the lowest energy structures of the intermediate (bid)Ni₂(CO)₅ and (bid)₂Ni₂(CO)₃ systems have Ni–Ni distances of ∼2.7 Å and intact diphosphine ligands. Furthermore, the lowest energy structures of the carbonyl-poorest (bid)Ni₂(CO)₄ and (bid)₂Ni₂(CO)₂ systems have shorter NiNi distances of ∼2.5 Å suggesting formal double bonds and retain the intact diphosphine ligands. This contrasts with the previously studied binuclear iron carbonyls [CH₃N(PF₂)₂]Fe₂(CO)₆ and [CH₃N(PF₂)₂]₂Fe₂(CO)₄ for which ligand cleavage to separate CH₃NPF₂ and PF₂ units rather than FeFe double bond formation occurs in the lowest energy structures. The experimental [(Me₂P)₂CH₂]₂Ni₂(CO)₄ structure with the boat form of the NiPCPNiPCP eight-membered lies ∼0.5 kcal mol⁻¹ in energy below the higher energy isomer with the chair form of the NiPCPNiPCP ring at the M06-L/TZP level of theory.
Agid:
6401037