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Reductive cyclization of 2-nitro-2′-hydroxy-5′-methylazobenzene to benzotriazole over K-doped Pd/γ-Al₂O₃

Author:
Wang, Bowei, Si, Leilei, Yuan, Yanyan, Li, Yang, Chen, Ligong, Yan, Xilong
Source:
RSC advances 2016 v.6 no.20 pp. 16766-16771
ISSN:
2046-2069
Subject:
catalysts, catalytic activity, potassium, salts, triazoles
Abstract:
A series of Pd/γ-Al₂O₃ catalysts modified by potassium salts were prepared and evaluated in the reductive cyclization of 2-nitro-2′-hydroxy-5′-methylazobenzene without additional base. These solid base-hydrogenation bifunctional catalysts were characterized and the results demonstrated that potassium salts could have an important impact on the properties and catalytic performance of Pd/γ-Al₂O₃.
Agid:
6402820