Jump to Main Content
A diiodo-BODIPY postmodified metal–organic framework for efficient heterogeneous organo-photocatalysis
- Quan, Ying, Li, Qiu-Yan, Zhang, Quan, Zhang, Wen-Qiang, Lu, Han, Yu, Jun-Hao, Chen, Jian, Zhao, Xinsheng, Wang, Xiao-Jun
- RSC advances 2016 v.6 no.29 pp. 23995-23999
- chemical bonding, coordination polymers, cycloaddition reactions, dehydrogenation, irradiation, light, photocatalysts, photosensitizing agents, topology, zirconium
- The organic photosensitizer diiodo-BODIPY has been covalently conjugated into a Zr(iv)-based metal–organic framework with UiO topology via postsynthetic modification, which serves as a highly active and recyclable heterogeneous photocatalyst for aerobic cross dehydrogenative coupling and oxidation/[3 + 2]cycloaddition reactions under visible light irradiation.