PubAg

Main content area

A diiodo-BODIPY postmodified metal–organic framework for efficient heterogeneous organo-photocatalysis

Author:
Quan, Ying, Li, Qiu-Yan, Zhang, Quan, Zhang, Wen-Qiang, Lu, Han, Yu, Jun-Hao, Chen, Jian, Zhao, Xinsheng, Wang, Xiao-Jun
Source:
RSC advances 2016 v.6 no.29 pp. 23995-23999
ISSN:
2046-2069
Subject:
chemical bonding, coordination polymers, cycloaddition reactions, dehydrogenation, irradiation, light, photocatalysts, photosensitizing agents, topology, zirconium
Abstract:
The organic photosensitizer diiodo-BODIPY has been covalently conjugated into a Zr(iv)-based metal–organic framework with UiO topology via postsynthetic modification, which serves as a highly active and recyclable heterogeneous photocatalyst for aerobic cross dehydrogenative coupling and oxidation/[3 + 2]cycloaddition reactions under visible light irradiation.
Agid:
6404924