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Copper-catalyzed N-formylation of amines with CO₂ under ambient conditions

Author:
Zhang, Suqi, Mei, Qingqing, Liu, Hangyu, Liu, Huizhen, Zhang, Zepeng, Han, Buxing
Source:
RSC advances 2016 v.6 no.38 pp. 32370-32373
ISSN:
2046-2069
Subject:
ambient temperature, amines, carbon dioxide, catalysts, copper, ethane
Abstract:
We carried out work on N-formylation of amines with CO₂ and PhSiH₃ to produce formamides catalyzed by a copper complex. It was found that the Cu(OAc)₂–bis(diphenylphosphino)ethane (dppe) catalytic system was very efficient for these kind of reactions at room temperature and 1 atm CO₂ with only 0.1 mol% catalyst loading.
Agid:
6405602