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A simple preparation of porous graphene nanosheets containing onion-like nano-holes with favorable high-rate Li-storage performance

Author:
Song, Ranran, Cao, Bin, Zhang, Di, Song, Huaihe
Source:
RSC advances 2016 v.6 no.68 pp. 63373-63377
ISSN:
2046-2069
Subject:
anodes, copper, copper nanoparticles, electric potential difference, graphene, lithium batteries, nanosheets, nitrites, phenolic resins
Abstract:
Porous graphene nanosheets (PGNs) containing onion-like nano-holes were simply prepared using copper nitrite as template and phenolic resin as carbon source by graphitization at 2800 °C. Based on the investigations of morphology and structure, PGNs were used as anode materials for lithium-ion batteries, and it was found that this PGN electrode exhibits a stable voltage plateau, endurable Li-storage capability and outstanding rate performance of 258 mA h g⁻¹ at 1 A g⁻¹ and 105 mA h g⁻¹ at 10 A g⁻¹ after 700 cycles, superior to those of other carbon anodes with a low voltage plateau. The reasons are discussed and explained in detail.
Agid:
6409664