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Interaction of organodialkoxysilanolates with carbon dioxide

Author:
Temnikov, M. N., Cherkun, N. V., Boldyrev, K. L., Zimovets, S. N., Kononova, E. G., Elmanovich, I. V., Gallyamov, M. O., Muzafarov, A. M.
Source:
RSC advances 2016 v.6 no.107 pp. 105161-105165
ISSN:
2046-2069
Subject:
carbon dioxide, carbonates, sodium
Abstract:
A series of organo(alkoxy)disiloxanes was obtained by the reaction of carbon dioxide with sodium alkoxy(organo)silanolates under high pressure as well as by bubbling CO₂ through the reaction mixture. It has been suggested that the reaction involves the intermediate formation of carbonate derivatives of sodium alkoxy(organo)silanolates.
Agid:
6412097