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A mechanochemical synthesis of submicron-sized Li₂S and a mesoporous Li₂S/C hybrid for high performance lithium/sulfur battery cathodes

Author:
Li, Xiang, Gao, Mingxia, Du, Wubin, Ni, Bo, Wu, Yuanhe, Liu, Yongfeng, Shang, Congxiao, Guo, Zhengxiao, Pan, Hongge
Source:
Journal of materials chemistry A 2017 v.5 no.14 pp. 6471-6482
ISSN:
2050-7496
Subject:
ambient temperature, batteries, carbon, carbonization, cathodes, electrochemistry, lithium, mechanochemistry, milling, polyacrylonitrile, porous media, sulfur
Abstract:
Lithium sulfide, Li₂S, is a promising cathode material for lithium–sulfur batteries (LSBs), with a high theoretical capacity of 1166 mA h g⁻¹. However, it suffers from low cycling stability, low-rate capability and high initial activation potential. In addition, commercially available Li₂S is of high cost and of large size, over ten microns, which further exacerbate its shortcomings as a sulfur cathode. Exploring new approaches to fabricate small-sized Li₂S of low cost and to achieve Li₂S cathodes of high electrochemical performance is highly desired. This work reports a novel mechanochemical method for synthesizing Li₂S of high purity and submicron size by ball-milling LiH with sulfur in an Ar atmosphere at room temperature. By further milling the as-synthesized Li₂S with polyacrylonitrile (PAN) followed by carbonization of PAN at 1000 °C, a Li₂S/C hybrid with nano-sized Li₂S embedded in a mesoporous carbon matrix is achieved. The hybrid with Li₂S as high as 74 wt% shows a high initial capacity of 971 mA h g⁻¹ at 0.1C and retains a capacity of 570 mA h g⁻¹ after 200 cycles as a cathode material for LSBs. A capacity of 610 mA h g⁻¹ is obtained at 1C. The synthesis method of Li₂S is facile, environmentally benign, and of high output and low cost. The present work opens a new route for the scalable fabrication of submicron-sized Li₂S and for the development of high performance Li₂S-based cathodes.
Agid:
6425010