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Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions

Author:
Andrews, Ryan J., ChitnisPresent address: Department of Chemistry, Dalhousie University, 6274 Coburg Road, Halifax, NS, B3H 4R2 Canada., Saurabh S., Stephan, Douglas W.
Source:
Chemical communications 2019 v.55 no.39 pp. 5599-5602
ISSN:
1364-548X
Subject:
Lewis acids, aldehydes, chemical reactions, ketones, olefin, phosphorus
Abstract:
The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C₆F₅)₄]₂1 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.
Agid:
6435564