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A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

Author:
Du, Xu-Sheng, Jia, Qiong, Wang, Chun-Yu, Meguellati, Kamel, Yang, Ying-Wei
Source:
Chemical communications 2019 v.55 no.40 pp. 5736-5739
ISSN:
1364-548X
Subject:
aldehydes, amines, aromatic hydrocarbons, chemical reactions, imines, mass spectrometry
Abstract:
We report a new mono-armed pillar[5]arene with the amino-substituent self-included in the pillarene cavity, which can stabilize the hemiaminals and imines formed from the reaction of aliphatic amines and aldehydes as monitored by mass spectroscopy.
Agid:
6444649