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Reversible insertion of CO into an aluminium–carbon bond

Author:
Kong, Richard Y., Crimmin, Mark R.
Source:
Chemical communications 2019 v.55 no.44 pp. 6181-6184
ISSN:
1364-548X
Subject:
aluminum, chemical bonding, chemical reactions
Abstract:
A [2.2.1] aluminium metallobicycle is capable of reversibly inserting CO to form a [2.2.2] metallobicycle at 100 °C. Computational studies reveal a highly asynchronous, but concerted, transition state for CO insertion. The coordination of CO to aluminium precedes C–C bond formation. The reversible migratory insertion of CO at aluminium thus mimics well-established transition-metal reactivity.
Agid:
6457249