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An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction

Author:
GaoThese authors contributed equally to this work., Ming-Liang, Qi, Mei-Hong, Liu, Lin, Han, Zheng-Bo
Source:
Chemical communications 2019 v.55 no.45 pp. 6377-6380
ISSN:
1364-548X
Subject:
catalysts, chemical compounds, condensation reactions
Abstract:
A novel strategy has been developed to construct a highly stable core–shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π–π stacking interaction. This hybrid material with spatially isolated antagonistic acid–base sites can effectively catalyze the deacetalization–Knoevenagel condensation cascade reaction.
Agid:
6458831