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Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates

Author:
Li, Qing, Sun, Xiaohua, Yang, Xiaoqin, Wu, Minghu, Sun, Shaofa, Chen, Xiuling
Source:
RSC advances 2019 v.9 no.28 pp. 16040-16043
ISSN:
2046-2069
Subject:
amination, amines, azides, chemical bonding
Abstract:
A facile and efficient approach to phosphoramidates was developed via amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P–N bond formation.
Agid:
6458909