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[Bi₇M₃(CO)₃]²⁻ (M = Co, Rh): a new architype of 10-vertex deltahedral hybrids by the unprecedented polycyclic η⁵-coordination addition of Bi₇³⁻ and trimetallic fragments

Author:
Li, Zhenyu, Ouyang, Dan, Xu, Li
Source:
Chemical communications 2019 v.55 no.47 pp. 6783-6786
ISSN:
1364-548X
Subject:
cobalt, ethylenediamines, redox reactions, rhodium
Abstract:
Redox reactions of K₅Bi₄ and CpCo(CO)₂/Rh(CO)₂(acac) (acac = acetylacetonate) in ethylenediamine (en) yielded the first Bi₇³⁻ adducts [Bi₇M₃(CO)₃]²⁻ (M = Co, 1a; Rh, 2a) that have a new architype 10-vertex deltahedral structure, resulting from the unprecedented polycyclic η⁵-coordination addition reaction of the Bi₇³⁻ cage and three MCO⁺ fragments.
Agid:
6463798