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Sorption kinetic of aroma compounds by edible bio-based films from marine-by product macromolecules: Effect of relative humidity conditions

Author:
Benbettaïeb, Nasreddine, O'Connell, Claire, Viaux, Anne-sophie, Bou-Maroun, Elias, Seuvre, Anne-Marie, Brachais, Claire-Hélène, Debeaufort, Frédéric
Source:
Food chemistry 2019 v.298 pp. 125064
ISSN:
0308-8146
Subject:
aldehydes, biopolymers, chitosan, edible films, gelatin, odor compounds, odors, phenol, physicochemical properties, plasticizers, relative humidity, sorption
Abstract:
Edible films based on gelatin and chitosan have high gas and aroma barrier properties. This study focused on their capability to sorbed/retain aroma compounds (1-hexanal, 2-hexen-1-ol, 1-hexanol, 3-hexanone and phenol) at three relative humidity level (≤2%, 53% or 84% RH). Whatever the relative humidity condition, the order of sorption is keton (3-hexanone) < aldehyde (1-hexanal) < aliphatic alcohols (2-hexen-1-ol and 1-hexanol) < phenol. This order could be related to the intrinsic chemical properties of aroma compounds. The increase in moisture enhanced the sorption at the highest RH for all the aroma compounds. However, a competition between water and aliphatic alcohols is observed at 53%RH. All compounds have an ideal sorption behaviour (logarithmic increase) except 1-hexanal. The sorption of 1-hexanal, 1-hexanol, 2-hexen-1-ol and 3-hexanone induced an antiplasticization of the network by increasing the film Tg by more than 5 °C. On the contrary, phenol was an efficient plasticizer at least as high as moisture.
Agid:
6483991