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The impact of additives on the retention of heavy metals in the bottom ash during RDF incineration

Author:
Jagodzińska, Katarzyna, Mroczek, Kazimierz, Nowińska, Katarzyna, Gołombek, Klaudiusz, Kalisz, Sylwester
Source:
Energy 2019 v.183 pp. 854-868
ISSN:
0360-5442
Subject:
additives, ammonium sulfate, antimony, bottom ash, cadmium, chromium, cobalt, copper, energy-dispersive X-ray analysis, fuels, halloysite, heavy metals, kaolinite, lead, manganese, mercury, nickel, scanning electron microscopy, sorbents, temperature, vanadium, zinc
Abstract:
Up to now, a few studies on the efficiency of heavy metal(-oid)s capture by a sorbent directly mixed with fuel, have been performed. For this reason, the main objective of the study is to determine whether or not such a solution is effective when RDF is incinerated. The paper presents a two-step analysis of the impact of three sorbents (ammonium sulphate, kaolinite and halloysite) in three dosages (2, 4 and 8 wt%) on heavy metal(-oid)s retention in the bottom ash. 12 heavy metal(-oid)s were taken into consideration - As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, V and Zn. Samples were incinerated in a lab-scale tubular reactor at two temperatures - 900 °C and 1100 °C. The first step of investigation constitutes ICP analysis of heavy metal(-oid)s content in the bottom ash, coupled with SEM/EDS analysis. Afterwards, the second step was to determine the stability of formed additive-heavy metal(-oid)s complexes via leachability tests in neutral and acid environments. The performed research has shown that ammonium sulphate is effective in Cr, Cu and Hg capture, halloysite – in Cd, Co, V and Mn capture, whereas kaolinite – in Pb capture.
Agid:
6495288