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Mild temperature amination of aryl iodides and aryl bromides with aqueous ammonia in the presence of CuBr and pyridyldiketone ligands

Author:
Abdine, Racha Abed Ali, Kurpik, Gracjan, Walczak, Anna, Aeash, Sultan Abu A., Stefankiewicz, Artur R., Monnier, Florian, Taillefer, Marc
Source:
Journal of catalysis 2019 v.376 pp. 119-122
ISSN:
0021-9517
Subject:
amination, ammonia, bromides, catalytic activity, copper, iodides, ligands, organobromine compounds, organoiodine compounds, temperature
Abstract:
Catalytic systems based on copper and simple ligands of ambidentate pyridyldiketone type were used in direct amination of aryl iodides and bromides with aqueous ammonia in one of the mildest conditions described in the literature, with reaction temperature ranging between 25 and 80 °C.
Agid:
6509075