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Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Author:
TeramaeThese authors contributed equally., Shota, Kito, Akane, Shingaki, Tomoteru, Hamaguchi, Yu, Yano, Yuuki, Nakayama, Takamori, Kobayashi, Yuko, Kato, Nobuki, Umezawa, Naoki, Hisamatsu, Yosuke, Nagano, Tetsuo, Higuchi, Tsunehiko
Source:
Chemical communications 2019 v.55 no.58 pp. 8378-8381
ISSN:
1364-548X
Subject:
alkanes, catalysts, catalytic activity, nitrogen oxides, oxidation, regioselectivity, ruthenium
Abstract:
Regioselective C–H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin–heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.
Agid:
6539533