Susceptibility of a heterogeneous catalyst, Rh/γ-alumina, to rapid structural change by exposure to NO
- Source:
- Chemical communications 2002 v. no.4 pp. 304-305
- ISSN:
- 1364-548X
- Subject:
- aluminum oxide, catalysts, chemical reactions, heat production, nitric oxide, particle size, rhodium
- Abstract:
- Metal particles in a Rh/γ-Al₂O₃ catalyst of differing particle size are oxidised by NO/He within 5 seconds at 313 K; rapid, highly exothermic dissociative chemisorption of NO is the initial step.
- Agid:
- 6571850
- https://doi.org/10.1039/b106846f