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Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

Author:
Lee, Jonghyuk, Twamley, Brendan, Richter-Addo, George B.
Source:
Chemical communications 2002 no.4 pp. 380-381
ISSN:
1364-548X
Subject:
chemical reactions, crystal structure, heme, ligands, models, nitrogen oxides, osmium, ruthenium
Abstract:
The metalloporphyrin nitrone complexes [M(oep)(CO)(DMPO)] (M = Ru, Os; oep = octaethylporphyrinato dianion; DMPO = 5,5-dimethyl-1-pyrroline N-oxide) have been prepared: the crystal structure of the Ru complex reveals a sole η¹-O binding mode of the nitrone ligand to the metal center.
Agid:
6572111