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Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon–carbon coupling reactions under room-temperature

Author:
Tatumi, Ryouta, Akita, Tomoki, Fujihara, Hisashi
Source:
Chemical communications 2006 no.31 pp. 3349-3351
ISSN:
1364-548X
Subject:
ambient temperature, catalysts, catalytic activity, chemical reactions, ligands, nanoparticles, palladium
Abstract:
A new bisphosphine ligand, C₈-BINAP, and C₈-BINAP-stabilized palladium nanoparticles have been prepared; C₈-BINAP was found to be an effective protecting ligand for preparing and stabilizing palladium nanoparticles with very small core size and narrow size distribution and the C₈-BINAP–Pd nanoparticles behave as an efficient catalyst for carbon–carbon coupling reactions at room temperature.
Agid:
6579935