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Regioselective ¹²CO/¹³CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hₒₓ state of [FeFe]-hydrogenase

Author:
Thomas, Christine M., Liu, Tianbiao, Hall, Michael B., Darensbourg, Marcetta Y.
Source:
Chemical communications 2008 no.13 pp. 1563-1565
ISSN:
1364-548X
Subject:
chemical reactions, enzymes, iron, models, regioselectivity
Abstract:
A mixed-valent Fe(ii)Fe(i) model of the Hₒₓ state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective ¹²CO/¹³CO exchange activity similar to that observed for Hₒₓ.
Agid:
6582134