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Palladium-catalysed aerobic oxidative Heck-type alkenylation of Csp³–H for pyrrole synthesis

Author:
Meng, Lingkui, Wu, Kun, Liu, Chao, Lei, Aiwen
Source:
Chemical communications 2013 v.49 no.52 pp. 5853-5855
ISSN:
1364-548X
Subject:
carbon-hydrogen bond activation, catalytic activity, chemical communication, chemical reactions, oxidants, oxygen, palladium, pyrroles
Abstract:
The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp³–H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp³–H metallation step was a slow step.
Agid:
6598609