PubAg

Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane

Author:

Chen, Wenyao, Ji, Jian, Duan, Xuezhi, Qian, Gang, Li, Ping, Zhou, Xinggui, Chen, De, Yuan, Weikang

Source:

Chemical communications 2014 v.50 no.17 pp. 2142-2144

ISSN:

1364-548X

Subject:

ammonia, catalysts, catalytic activity, dehydrogenation, hydrogen production, nanomaterials, oxidation, oxygen, particle size, texture

Abstract:

We demonstrate an unprecedented H₂ generation activity in the hydrolytic dehydrogenation of ammonia borane over acid oxidation- and subsequent high temperature-treated CNT immobilized Pt nanocatalysts to combine the merits of defect-rich and oxygen group-deficient surfaces and unique textural properties of supports as well as optimum particle size of Pt.

Agid:

6600652

http://dx.doi.org/10.1039/c3cc48027e