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Well-defined transition metal hydrides in catalytic isomerizations
- Larionov, Evgeny, Li, Houhua, Mazet, Clément
- Chemical communications 2014 v.50 no.69 pp. 9816-9826
- catalysts, catalytic activity, hydrides, isomerization, transition elements
- This Feature Article intends to provide an overview of a variety of catalytic isomerization reactions that have been performed using well-defined transition metal hydride precatalysts. A particular emphasis is placed on the underlying mechanistic features of the transformations discussed. These have been categorized depending upon the nature of the substrate and in most cases discussed following a chronological order.