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A new class of rare earth tetrapyrrole sandwich complexes containing corrole and phthalocyanine macrocycles: synthesis, physicochemical characterization and X-ray analysis

Author:
Lu, Guifen, Yan, Sen, Shi, Mengying, Yu, Wenhan, Li, Jing, Zhu, Weihua, Ou, Zhongping, Kadish, Karl M.
Source:
Chemical communications 2015 v.51 no.12 pp. 2411-2413
ISSN:
1364-548X
Subject:
X-ray diffraction, chemical reactions, chemical structure, electrochemistry, europium, physicochemical properties, spectroscopy
Abstract:
The first europium triple-decker tetrapyrrole with mixed corrole and phthalocyanine macrocycles was synthesized and characterized by spectroscopic and electrochemical methods. The molecular structure was characterized by single-crystal X-ray diffraction and showed the corrole to be in the middle of the sandwich with phthalocyanine macrocycles at each extreme.
Agid:
6608386