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Co2+ anchored on surface-functionalized PET non-woven fabric and used as high efficiency monoatom-like catalyst for activating Oxone in water

Author:
Liu, Yinjie, Zhou, Xiying, Wang, Minglei, Zhang, Maojiang, Shen, Rongfang, Zhang, Yumei, Hu, Jiangtao, Wu, Guozhong
Source:
The Science of the total environment 2020 v.699 pp. 134286
ISSN:
0048-9697
Subject:
activation energy, catalysts, catalytic activity, cobalt, fabrics, free radicals, ions, manufacturing, pH, pollution, polyethylene terephthalates, polymerization, sodium chloride, temperature
Abstract:
Fenton-like processes have emerged as most promising techniques for generating reactive oxygen-containing radicals to deal with increasing levels of environmental pollution. Developing novel catalysts with simple manufacturing requirements, excellent activity levels, and stability remains a long-term goal in terms of practical application. So herein, a new polyethylene terephthalate (PET) non-woven fabric based composite catalyst has been fabricated, using radiation-induced graft polymerization of a functionalized group to chelate Co2+ ions as heterogeneous catalysts in peroxymonosulfate (Oxone) activation. Several impact factors, including catalyst dosage, Oxone concentration, reaction temperature, pH value, Co2+ precipitation ratio (of Co@PET at different pH values), and highly concentrated NaCl have been investigated here. Notably, Co@PET has shown the lowest activation energy of any reported catalyst, for degrading RhB by activating Oxone. Interestingly, as experimental RhB and Oxone solutions were passed through single Co@PET sheets, the RhB was decomposed into a colorless solution in the penetration process. Based on radical trapping and quenching experiments, a channel was determined to dominate RhB degradation, and furthermore, Co@PET could be re-used for RhB degradation by activating Oxone. These results showed that Co@PET effectively provided improved Fenton-like catalytic performance and stability, and was suitable for practical applications.
Agid:
6660641