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A novel N–N bond cleavage in 1,5-diaminotetrazole: synthesis and characterization of 5-picrylamino-1,2,3,4-tetrazole (PAT)

Author:
Tang, Yongxing, Yang, Hongwei, Ju, Xuehai, Huang, Hui, Lu, Chunxu, Cheng, Guangbin
Source:
Journal of materials chemistry A 2014 v.2 no.12 pp. 4127-4131
ISSN:
2050-7496
Subject:
X-ray diffraction, chemical bonding, cleavage (chemistry), organochlorine compounds
Abstract:
The reaction of 1,5-diaminotetrazole with picryl chloride (PiCl) forms 5-picrylamino-1,2,3,4-tetrazole (PAT) rather than the expected 1-picrylamino-5-amino-1,2,3,4-tetrazole or 5-picrylamino-1-amino-1,2,3,4-tetrazole. The structure of PAT was confirmed by single-crystal X-ray diffraction. Some of the energetic properties of the synthesized compound were also studied.
Agid:
6705933