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Sorption–Desorption of Carbamazepine from Irrigated Soils

Author:
Williams, C. F., Williams, C. F., Adamsen, F. J.
Source:
Journal of environmental quality 2006 v.35 no.5 pp. 1779
ISSN:
1537-2537
Subject:
irrigated soils, silt loam soils, sewage effluent, wastewater irrigation, irrigation water, soil pollution, polluted soils, drugs, water pollution, groundwater contamination, leaching, adsorption, desorption, sorption isotherms, Utah
Abstract:
Th anti-seizure medication carbamazepine is often found in treated sewage effluent and environmental samples. Carbamazepine has been shown to be very persistent in sewage treatment, as well as ground water. Due to environmental persistence, irrigation with sewage effluent could result in carbamazepine contamination of surface and ground water. To determine the potential for leaching of carbamazepine, a series of adsorption and desorption batch equilibrium experiments were conducted on irrigated soils. It was found that carbamazepine adsorption to biosolid-amended (T) soils had a of 19.8 vs. 12.6 for unamended soil. Based on adsorption, carbamazepine leaching potential would be categorized as low. During desorption significant hysteresis was observed and increased for both soils. Desorption isotherms also indicate a potential for irreversibly bound carbamazepine in the T soil. Results indicate that initial removal of carbamazepine via adsorption from irrigation water is significant and that desorption characteristics would further limit the mobility of carbamazepine through the soil profile indicating that carbamazepine found in sewage effluent used for irrigation has a low leaching potential.
Agid:
7375
Handle:
10113/7375