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Enhancement of Structural, Electrochemical, and Thermal Properties of High-Energy Density Ni-Rich LiNi₀.₈₅Co₀.₁Mn₀.₀₅O₂ Cathode Materials for Li-Ion Batteries by Niobium Doping

Author:
Yehonatan Levartovsky, Arup Chakraborty, Sooraj Kunnikuruvan, Sandipan Maiti, Judith Grinblat, Michael Talianker, Dan Thomas Major, Doron Aurbach
Source:
ACS applied materials & interfaces 2021 v.13 no.29 pp. 34145-34156
ISSN:
1944-8252
Subject:
cathodes, density functional theory, durability, electrochemistry, niobium, oxygen, thermal stability
Abstract:
Ni-rich layered oxide LiNi₁ – ₓ – yCoₓMnyO₂ (1 – x – y > 0.5) materials are favorable cathode materials in advanced Li-ion batteries for electromobility applications because of their high initial discharge capacity. However, they suffer from poor cycling stability because of the formation of cracks in their particles during operation. Here, we present improved structural stability, electrochemical performance, and thermal durability of LiNi₀.₈₅Co₀.₁Mn₀.₀₅O₂(NCM85). The Nb-doped cathode material, Li(Ni₀.₈₅Co₀.₁Mn₀.₀₅)₀.₉₉₇Nb₀.₀₀₃O₂, has enhanced cycling stability at different temperatures, outstanding capacity retention, improved performance at high discharge rates, and a better thermal stability compared to the undoped cathode material. The high electrochemical performance of the doped material is directly related to the structural stability of the cathode particles. We further propose that Nb-doping in NCM85 improves material stability because of partial reduction of the amount of Jahn–Teller active Ni³⁺ ions and formation of strong bonds between the dopant and the oxygen ions, based on density functional theory calculations. Structural studies of the cycled cathodes reveal that doping with niobium suppresses the formation of cracks during cycling, which are abundant in the undoped cycled material particles. The Nb-doped NCM85 cathode material also displayed superior thermal characteristics. The coherence between the improved electrochemical, structural, and thermal properties of the doped material is discussed and emphasized.
Agid:
7461467