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Stereo- and regioselective glycosylation of 4-deoxy-ε-rhodomycinone

Author:
Ekholm, Filip S., Lagerquist, Lucas, Leino, Reko
Source:
Carbohydrate research 2011 v.346 no.6 pp. 858-862
ISSN:
0008-6215
Subject:
anthracyclines, chemical structure, glycosylation, stereochemistry
Abstract:
A method for the glycosylation of anthracyclines featuring benzoylated imidate donors has been developed and utilized in the synthesis of glycosylated 4-deoxy-ε-rhodomycinone derivatives. Due to its high efficiency, regioselectivity, stereoselectivity, and operational simplicity, the method should prove valuable to researchers working with glycosylation of tetracyclic compounds.
Agid:
855850